Electrochemically reduced graphene oxide modified with electrodeposited thionine and horseradish peroxidase for hydrogen peroxide sensing and inhibitive measurement of chromium

The reaction of ferrous horseradish peroxidase with hydrogen peroxide.

Hydrogen peroxide reacts with ferrous horseradish peroxidase and converts it to oxyperoxidase in a sequence of two reactions. The first is the reaction of ferrous peroxidase with HzOz to form Compound II; the second is the reaction of Compound II with HzOz to form oxyperoxidase. Both reactions follow second order kinetics, being first order with respect to each of the reactants. They proceed wi...

Redox Response of Reduced Graphene Oxide-Modified Glassy Carbon Electrodes to Hydrogen Peroxide and Hydrazine

The surface of a glassy carbon (GC) electrode was modified with reduced graphene oxide (rGO) to evaluate the electrochemical response of the modified GC electrodes to hydrogen peroxide (H₂O₂) and hydrazine. The electrode potential of the GC electrode was repeatedly scanned from -1.5 to 0.6 V in an aqueous dispersion of graphene oxide (GO) to deposit rGO on the surface of the GC electrode. The s...

Hydrogen Peroxide Biosensors Based on Horseradish Peroxidase and Hemoglobin

Hydrogen peroxide (H2O2) plays a pivotal role in various industrial applications [1]. It is an essential mediator in pharmaceutical, clinical, and environmental research. In addition, it is a byproduct of highly selective oxidases and an important contaminant in several industrial products and wastes [2]. Therefore, a reliable and economical method for the determination of H2O2 is of great sign...

Graphene electrode modified with electrochemically reduced graphene oxide for label-free DNA detection.

A novel printed graphene electrode modified with electrochemically reduced graphene oxide was developed for the detection of a specific oligonucleotide sequence. The graphene oxide was immobilized onto the surface of a graphene electrode via π-π bonds and electrochemical reduction of graphene oxide was achieved by cyclic voltammetry. A much higher redox current was observed from the reduced gra...

Electrically and Electrochemically Active Composite Based on Polyester/Reduced Graphene Oxide/Polypyrrole with Remarkable Washing Durability